Some Physical Properties of Cobalt-Antimony Ferrites
DOI:
https://doi.org/10.54172/mjsc.v14i1.880Keywords:
ferrites, ceramic technique, firing process, soaking time, spinel structure, Mossbauer spectra, Infrared spectroscopy, and Reitveld methodAbstract
Different samples for ferrite compounds of system Co1+xSnxFe2-2xO4, where hence x takes values 0.25, 0.5, 0.75 and 1, were synthesized by using ceramic technique method from their metal oxides of their purity more than 99.9%. The firing process was done at temperature 1200°C, and a soaking time of about 24 hours. X-ray diffraction (XRD) patterns of all used samples showed the cubic phase of spinel structure. The infrared spectra results have been obtained and analyzed, also the frequency bands were assigned, and it was found to be compositional parameter. The Mossbauer spectra technique at room temperature also has been used, and it indicates that all the compounds are principally paramagnetic. Only the iron rich compound is order ferrimagnetically and has magnetic transition temperature higher than room temperature. The crystal structure was refined for all the samples using whole pattern-fitting analysis of Reitveld method.
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References
Alder. E. and H. Pfeiffer, Soft Ferrites Properties, IEEE Trans. Mag. 10, 172 (1974). DOI: https://doi.org/10.1109/TMAG.1974.1058314
Tsunekawa, Hiroshi, et al., Microstructure and properties of commercial grade ferrites, IEEE Trans. Mag. 15, 1855 (1976). DOI: https://doi.org/10.1109/TMAG.1979.1060382
G. Albanese, M. Carbouccluo and G. Asti, Characteristics and uses of ferrites, Appl. Phys. 11, 174 (1976).
Araki, Shigeo and Okutani, Katsunobu, Ferrites2-the state of the ferrite industry (1979).
N. Greenwood and T. G. Gibb, Mossbauer effect spectroscopy, Chapman and Hall, London, (1971). DOI: https://doi.org/10.1007/978-94-009-5697-1_1
T. G. Stinjntes, J. Klerk, C. J. M. Rooymans, A. Broese Vangroenou, R. F. Pearson, J. E. Knowleds and P. Rankin, Ferrite, Proc. Internal. Conference 191 (1970).
T. G. Stijnties, J.Klerk, C. J. M. Rooymans, A. Broese Van Groenou, R. F. Pearson, J. E. Knowles and P. Rankin, Ferrites, Proc. Internal. Conference 199 (1970).
G. M. Kalvius, and E. Kankeleit, "Recent Improvement in instrumentation and methods of Mossbauer Spectroscopy and its Application", International Atomic Energy, Agency, Vienna, 9 (1972).
G. Kulkarni, and H. H. Joshi, Solid State Commun. 53, 1005 (1985). DOI: https://doi.org/10.1016/0038-1098(85)90479-X
J. S. Baijal, C. Prakash, P. Kishan and K. K. Laroi, J Phys. C: Solid State, 17, 5993 (1984). DOI: https://doi.org/10.1088/0022-3719/17/33/010
Van Uitert, L.G., Low magnetic saturation ferrites for microwave applications, J: Appl. Phys., 26, 1289 (1955). DOI: https://doi.org/10.1063/1.1721895
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