Adsorption Isotherm of an Insecticide Methomyl onto Natural Clay

Authors

  • Mohammad S El-Geundi Chemical Engineering Department, Faculty of Engineering, Omar Al-Mukhtar University
  • Assanousi A Abufares Chemical Engineering Department, Faculty of Engineering, Omar Al-Mukhtar University

DOI:

https://doi.org/10.54172/mjsc.v28i1.144

Keywords:

methomyl, Natural clay, Adsorption isotherm, Isotherm models

Abstract

Adsorption isotherm of an insecticide methomyl onto natural clay has been investigated. The experimental data were fitted to isotherm models, Langmuir, Freundlich and Redlich Peterson. The Langmuir model fit the experimental data significantly better than Freundlich and Redlich Peterson models. A dimensionless separation factor, Ř, was used to judge the favorable adsorption. A chart based on material balance using single batch adsorber was constructed for different percentage of methomyl removal using the Langmuir model where the mass of natural clay required to treat a specified volume of solution is calculated. The effect of temperature showed the exothermic nature of the process. The enthalpy change, ΔH, of adsorption has been evaluated and it has a value of (-17.54 kJ/mol).

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References

Alam, J.B. (1996) Risk assessment and management of selected pesticides generally used in Bangladesh, M. Tech. Thesis, Bangladesh University of Engineering and Technology.

Alkan, M., Kalay, B., Gogan M. and Demirbas, O. (2008) Removal of copper ions from aqueous solution by kaolinite and batch design. J. Hazard. Mater, 153, 867-876. DOI: https://doi.org/10.1016/j.jhazmat.2007.09.047

Bonne, P.A.C., Beerendonk, E.F., Van der Hoek, J.P. and Hofman, J.A.M.H. (2000) Retention of herbicides and pesticides in relation to aging of RO membranes. Desalination, 132, 189-193. DOI: https://doi.org/10.1016/S0011-9164(00)00148-X

Boussahel, R., Bouland, S., Moussaoui, K. M. and Montiel, A. (2000) Removal of pesticide residues in water using the nanofiltration process. Desalination, 132, 205-209. DOI: https://doi.org/10.1016/S0011-9164(00)00151-X

Brunauer, S., Emmett, P.H. and Teller, E. (1932) Adsorption of gases in multimolecular layers. J Am Chem Soc, 6, 309-319. DOI: https://doi.org/10.1021/ja01269a023

Chan, L.S., Cheung, W.H. and McKay, G. (2008) Adsorption of acid dyes by bamboo derived activated carbon. Desalination, 218, 304-312. DOI: https://doi.org/10.1016/j.desal.2007.02.026

Devitt, E.C. and Wiesner, M.R. (1998) Dialysis investigations of atrazine-organic matter inter-actions and the role of a divalent metal. Environ. Sci. Technol., 32, 232-237. DOI: https://doi.org/10.1021/es970179m

Giles, C.H., Macewan, T.H., Nakhwa, S.N. and Smith, D. (1960) A system of classification of solution adsorption isotherms, and its use in diagnosis of adsorption mechanisms. J. Chem. Soc., 4, 3973-3993. DOI: https://doi.org/10.1039/jr9600003973

Gosselin, R.E., Smith, R.P. and Hodge H.C. (1984) Clinical toxicology of commercial products. Baltimore: Williams and Wilkins; 5th edition, 267-333.

Hatfield, J.L., Wesley, C.K., Prueger, J.H. and Pfeiffer, R.L. (1996) Herbicide and nitrate distribution in central Iowa rainfall. J. Environ. Qual., 25, 259-264. DOI: https://doi.org/10.2134/jeq1996.00472425002500020008x

Khlifi, R., Belbahri, L., Woodward, S., Ellouz, M., Dhouib, A., Sayadi, S. and Mechichi, T. (2010) Decolourization and detoxification of textile industry wastewater by the laccase-mediator system. Journal of Hazardous Materials, 175, 802-808. DOI: https://doi.org/10.1016/j.jhazmat.2009.10.079

Kiriakopoulos, G., Doula, D. and Anagnostopoulos, E. (2005) Adsorption of pesticides on porous polymeric adsorbents. Chemical Engineering Science, 60, 1177-1186. DOI: https://doi.org/10.1016/j.ces.2004.09.080

Mangat, S.S. and Elefsiniotis, P. (1999) Biodegradation of the herbicide 2,4-dichlorophenoxy-acetic acid (2,4-D) in sequencing batch reactors. Water Research, 33, 861-867. DOI: https://doi.org/10.1016/S0043-1354(98)00259-0

McKay, G., El-Geundi, M.S. and Nassar, M.M. (1987) Equilibrium studies during the removal of dyestuffs from aqueous solutions using bagasse pith. Water Res., 21, 1513-1520. DOI: https://doi.org/10.1016/0043-1354(87)90135-7

McKay, G., Otterburn, M.S. and Aga, A.J. (1985) Fullers earth and fired clay as adsorbents for dyestuffs. Water Air Soil Pollut., 24, 307-322. DOI: https://doi.org/10.1007/BF00161790

Rao, V.S. (1996) Contamination of village drinking water ponds with pesticide residue. Indian J Environmental protection, 16, 505-509.

Singh, B.K. and Rawat, N.S. (1994) Comparative sorption equilibrium studies of toxic phenols on fly ash and impregnated fly ash. J. Chem. Technol. Biotechnol., 61, 307-317. DOI: https://doi.org/10.1002/jctb.280610405

Treybal, R.E. (1985) Mass transfer operation. Mc Graw-Hill Book Company; 3rd edition, 565-612.

Weber, J.B., Ward, T.M. and Weed, S.B. (1968) Adsorption and desorption of diquat, paraquat, prometone, and 2,4-D by charcoal and exchange resins. Soil Science Society of America Journal, 32, 197-200. DOI: https://doi.org/10.2136/sssaj1968.03615995003200020015x

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Published

2022-03-27

How to Cite

El-Geundi, M. S., & Abufares, A. A. (2022). Adsorption Isotherm of an Insecticide Methomyl onto Natural Clay. Al-Mukhtar Journal of Sciences, 28(1), 46–59. https://doi.org/10.54172/mjsc.v28i1.144

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Research Articles